Fluxional Organometallic And Coordination Compounds Physical Organometallic Chemistry Volume 4 Marcel Gielen by Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer(eds.) 9780470858394, 9780470858455, 0470858397, 0470858451 instant download after payment.

This series offers leading contributions by well-known chemists reviewing the state of the art of this wide research area. Physical organometallic chemistry aims to develop new insights and to promote novel interest and investigations applicable to organometallic chemistry.

This volume focuses on several important topics on fluxionality in organometallic and coordination chemistry, reviewed by experts in each of the respective fields. It is intended to provide both authoritative concepts and stimulating ideas in order to tackle dynamics from different angles, aiming at an interdisciplinary approach. The fascinating fluxionality of metal-ligand interactions has been in the centre of interest ever since modern coordination and organometallic chemistry started, and has expanded towards bioinorganic chemistry, catalysis and materials sciences.

• Provides information on some of the most relevant physical methods for studying dynamic processes
• Presents numerous examples of dynamic behavior, demonstrating the efficiency of the respective method and stimulating further applications
• Connects main group, transition metal and solid state chemistry in the question for dynamics

Content:
Chapter 1 Polyhedral Dynamics and the Jahn–Teller Effect (pages 1–39): R. Bruce King
Chapter 2 NMR Studies of Intramolecular Dynamics in Allylic Type Triorganoboranes (pages 41–83): Ilya D. Gridnev and Oleg L. Tok
Chapter 3 Dynamic Behavior of Group 5 and 6 Transition Metal Complexes with NMR (pages 85–129): Sergei G. Sakharov
Chapter 4 Conformational Mobility in Chelated Square?Planar Rh, Ir, Pd, and Pt Complexes (pages 131–161): Pablo Espinet and Juan A. Casares
Chapter 5 Dynamic and Kinetic Aspects of Metallodrugs by NMR (pages 163–217): Fei Li and Hongzhe Sun
Chapter 6 Dynamics by EPR: Picosecond to Microsecond Time Scales (pages 219–242): Sabine van Doorslaer and Gunnar Jeschke
Chapter 7 µSR Studies of Molecular Dynamics in Organometallics (pages 243–265): Upali A. Jayasooriya
Chapter 8 Proton Dynamics in Solids: Vibrational Spectroscopy with Neutrons (pages 267–304): Francois Fillaux