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Hypervalent Iodine Chemistry Modern Developments in Organic Synthesis 1st Edition by Thomas Wirth ISBN 3540441077 9783540441076

  • SKU: BELL-2161846
Hypervalent Iodine Chemistry Modern Developments in Organic Synthesis 1st Edition by Thomas Wirth ISBN 3540441077 9783540441076
$ 31.00 $ 45.00 (-31%)

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Hypervalent Iodine Chemistry Modern Developments in Organic Synthesis 1st Edition by Thomas Wirth ISBN 3540441077 9783540441076 instant download after payment.

Publisher: Springer-Verlag Berlin Heidelberg
File Extension: PDF
File size: 4.14 MB
Pages: 248
Author: Thomas Wirth (auth.), Prof. Dr. Thomas Wirth (eds.)
ISBN: 3540441077
Language: English
Year: 2003
Edition: 1

Product desciption

Hypervalent Iodine Chemistry Modern Developments in Organic Synthesis 1st Edition by Thomas Wirth ISBN 3540441077 9783540441076 by Thomas Wirth (auth.), Prof. Dr. Thomas Wirth (eds.) 3540441077 instant download after payment.

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Product details:

ISBN 10: 3540441077 
ISBN 13: 9783540441076
Author: Thomas Wirth

Embarking on a new millennium, the book in hands describes the recent developments of organsoselenium chemistry in all facets. Various distinguished scientists have contributed, with their skill and expertise, making this book a valuable source for synthetic oriented organic chemists and for those, who want to get a first insight into the chemistry of selenium.

Hypervalent Iodine Chemistry Modern Developments in Organic Synthesis 1st Table of contents:

  1. Topics in Current Chemistry
  2. Organoselenium Chemistry
  3. Volume Editor
  4. Editorial Board
  5. Topics in Current Chemistry Now Also Available Electronically
  6. Preface
  7. Contents
  8. Contents of Volume 204 Organosulfur Chemistry I
  9. Contents of Volume 205 Organosulfur Chemistry II
  10. Introduction and General Aspects
  11. References
  12. Electrophilic Selenium, Selenocyclizations
  13. Introduction
  14. The Production of the Electrophilic Reagents
  15. Addition Reactions to Carbon-Carbon Double Bonds
  16. Oxyselenenylation Reactions
  17. Asymmetric Oxyselenenylation Reactions
  18. Addition of Nitrogen Nucleophiles
  19. Selenocyclizations
  20. Oxygen Nucleophiles
  21. Nitrogen Nucleophiles
  22. Competition Between Oxygen and Nitrogen
  23. Competition Between Different Nitrogens
  24. Carbon Nucleophiles
  25. 5Selenium Catalyzed Conversions
  26. One-pot Sequential Selenenylation and Deselenenylation Reactions
  27. Deselenenylation with Substitution
  28. Deselenenylation with Elimination
  29. References
  30. Nucleophilic Selenium
  31. Introduction
  32. Preparation of Nucleophilic Selenium Species
  33. Insertion of Selenium into Organolithium or Grignard Reagents
  34. Reduction of Diselenides, Selenocyanates, and Elemental Selenium
  35. Use of Alkali Metals and Hydrides
  36. Use of Alkali Borohydrides
  37. Use of Hydrazines
  38. Use of Samarium Reagents
  39. Electrochemical Reduction
  40. Other Methods
  41. Reactions of Nucleophilic Selenium Species
  42. Reactions with Halides
  43. Ring Opening of Epoxides and Cyclic Ethers
  44. Reactions with Esters and Lactones
  45. Michael Addition
  46. Miscellaneous
  47. Selenium Bonded to Main Group Elements
  48. Group 13 Elements
  49. Boron
  50. Aluminum
  51. Indium
  52. Group 14 Elements
  53. Silicon
  54. Tin
  55. Applications to Asymmetric Ring Opening of Epoxides
  56. Applications to Solid-Phase Synthesis
  57. Perspectives
  58. References
  59. Radical Reactions Using Selenium Precursors
  60. Introduction
  61. Radical Precursors for Tin Mediated Reactions and Related Processes
  62. Generation of Alkyl Radicals
  63. Radical Precursors from Nucleophilic Selenolates
  64. Radical Precursors from Electrophilic Selenium
  65. Radical Precursors from Selenium Stabilized Carbanions
  66. Selenides as Building Blocks
  67. Generation of Carbonyl-Substituted and Related Alkyl Radicals
  68. Generation of Alkoxy- and Amino-Substituted Alkyl Radicals
  69. Acyl and Related Radicals
  70. Seleno Group Transfer Reactions
  71. Carbon-Centered Radicals
  72. Selenosulfonation
  73. Selenosulfonation of Alkenes
  74. Selenosulfonation of Alkynes
  75. Phenylselenyl Radical Mediated Reactions
  76. From Selenoboranes
  77. From Selenols
  78. Picosecond Radical Kinetics with Benzeneselenol
  79. Polarity Reversal Catalysis with Benzeneselenol
  80. Diselenides as Radical Traps
  81. Selenodecarboxylation
  82. Azidoselenenylation
  83. Miscellaneous Reactions
  84. Miscellaneous
  85. Radical Substitution at Selenium
  86. Alkoxyl Radicals from Tetravalent Selenium
  87. Conclusions
  88. References
  89. Selenium-Stabilized Carbanions
  90. Introduction
  91. Generation and Reactivity of a-Selanylalkylmetals, a-Seleninyl and a-Selenonyl Analogues
  92. Recent Synthetic Applications
  93. a-Deprotonation of Selenides, Selenoxides and Selenones
  94. Se/Li Exchange Reactions
  95. Reactivity of Lithium and Potassium a-Selanyl Enolates
  96. Mechanistic Aspects
  97. b-Phenylselanyl Enoxysilanes
  98. Synthetic Applications
  99. Reactivity of a-Selanyl a,b-Unsaturated Carbonyl Compounds
  100. Reactivity of Other a-Functionalized Selenium-Stabilized Carbanions
  101. a-Cyano Selenium-Stabilized Carbanions
  102. a-Phosphono Selenium-Stabilized Carbanions
  103. a-Arenesulfanyl Selenium-Stabilized Carbanions
  104. Synthesis and Reactivity of a-Selanylvinylmetal Derivatives
  105. Generation from Vinylic Selenides and Ketene Selenoacetals
  106. Cuprate Addition to Acetylenic Selenides
  107. Hydrostannylation of Acetylenic Selenides
  108. Hydrozirconation of Acetylenic Selenides
  109. Hydroboration of Acetylenic Selenides
  110. References
  111. Selenium at Higher Oxidation State
  112. Introduction
  113. Trivalent, Tricoordinated Selenonium Salts
  114. Tetravalent, Dicoordinated Derivatives
  115. Tetravalent, Tricoordinated Derivatives
  116. Tetravalent, Tetracoordinated Derivatives
  117. Hexavalent, Tetracoordinated Derivatives
  118. Hexavalent, Hexacoordinated Derivatives
  119. References
  120. Selenocarbonyls
  121. Overview
  122. Structures
  123. Syntheses
  124. With Electrophilic Selenium
  125. With Nucleophilic Selenium
  126. With Carbon Diselenide
  127. Reactions
  128. With Olefins and Acetylenes
  129. With Nucleophiles
  130. With Electrophiles
  131. Via Eneselenolates
  132. With Inorganic Metals and Metal Salts
  133. Metal Complexes and Their Properties
  134. References
  135. Selenoxide Elimination and [2,3]Sigmatropic Rearrangement
  136. Introduction
  137. Optically Active Selenoxides
  138. Selenoxide Elimination
  139. Enantioselective Selenoxide Elimination Producing Optically Active Allenes and a,b-Unsaturated Keton
  140. Diastereoselective Selenoxide Elimination Producing Optically Active Allenecarboxylic Esters
  141. [2,3]Sigmatropic Rearrangement via Allylic Selenoxides
  142. Enantioselective [2,3]Sigmatropic Rearrangement Producing Optically Active Allylic Alcohols
  143. Diastereoselective [2,3]Sigmatropic Rearrangement Producing Optically Active Allylic Alcohols
  144. [2,3]Sigmatropic Rearrangement via Allylic Selenimides
  145. Optically Active Selenimides
  146. Enantioselective [2,3]Sigmatropic Rearrangement Producing Optically Active Allylic Amines
  147. Diastereoselective [2,3]Sigmatropic Rearrangement Producing Optically Active Allylic Amines
  148. [2,3]Sigmatropic Rearrangement via Allylic Selenium Ylides
  149. Optically Active Selenium Ylides
  150. Enantioselective [2,3]Sigmatropic Rearrangement Producing Optically Active Homoallylic Chalcogenides
  151. Diastereoselective [2,3]Sigmatropic Rearrangement Producing Optically Active Homoallylic Chalcogenid
  152. References
  153. Selenium Compounds as Ligands and Catalysts
  154. Introduction
  155. Diselenides as Chiral Ligands for Asymmetric Hydrosilylation of Ketones and Related Reactions
  156. Diselenides as Chiral Ligands for Asymmetric Hydrosilylation of Ketones and Imines
  157. Diselenides as Chiral Ligands for Asymmetric Transfer Hydrogenation of Ketones
  158. Chiral Diselenides and Selenides as Procatalysts for Diethylzinc Addition to Aldehydes
  159. Chiral Diselenides as Procatalysts in Diethylzinc Addition to Aldehydes
  160. Chiral Ferrocenylselenium Aminoalcohols as Procatalysts in Diethylzinc Addition to Aldehydes
  161. Catalytic Reactions Using Organoselenium Compounds
  162. Catalytic Allylic Oxidation of Alkenes Using Diselenides
  163. Catalytic Epoxidation of Alkenes
  164. Asymmetric Catalytic Allylic Oxidation of Alkenes Using Chiral Diselenides
  165. References
  166. Author Index Volume 201-208

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