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78 reviewsDevelopments in the use of water as a solvent for organic synthesis have reached the point where it could now be considered a viable solvent for many organic reactions. Organic Reactions in Water demonstrates the underlying principles of using water as a reaction solvent and, by reference to a range of reaction types and systems, it’s effective use in synthetic organic chemistry. Written by an internationally respected team of contributors, and with a strong focus on the practical use of water as a reaction medium, this book illustrates the enormous potential of water for the development of new and unique chemistries and synthetic strategies, while at the same time offering a much reduced environmental impact.Content:
Chapter 1 A Fifty?Year Perspective on Chemistry in Water (pages 1–28): Ronald Breslow
Chapter 2 Structure and Properties of Water (pages 29–59): Jan B.F.N. Engberts
Chapter 3 Acid Catalysis in Water (pages 60–91): Chikako Ogawa and Shu Kobayashi
Chapter 4 Metal?Mediated C?C Bond Formations in Aqueous Media (pages 92–145): Chao?Jun Li
Chapter 5 Pericyclic Reactions in Aqueous Media (pages 146–184): Francesco Fringuelli, Oriana Piermatti, Ferdinando Pizzo and Luigi Vaccaro
Chapter 6 Catalyzed Reductions in Aqueous Media (pages 185–214): T.V. Rajanbabu and Seunghoon Shin
Chapter 7 Oxidations (pages 215–235): Roger A. Sheldon
Chapter 8 Nucleophilic Additions and Substitutions in Water (pages 236–255): Denis Sinou
Chapter 9 Reactions in Nearcritical Water (pages 256–300): C.L. Liotta, J.P. Hallett, P. Pollet and C.A. Eckert
Chapter 10 Biocatalysis in Water (pages 301–349): Kaoru Nakamura and Tomoko Matsuda
Chapter 11 Chemistry ‘On Water’ – Organic Synthesis in Aqueous Suspension (pages 350–365): Sridhar Narayan, Valery V. Fokin and K. Barry Sharpless
Chapter 12 Water as a Reaction Solvent – an Industry Perspective (pages 366–397): Ernst Wiebus and Boy Cornils
