Organolithiums in Enantioselective Synthesis 2003rd Edition by David M Hodgson ISBN 3540001042 9783540001041 by David M. Hodgson 3540001042 instant download after payment.

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ISBN 10: 3540001042 
ISBN 13: 9783540001041
Author: David M Hodgson

Organolithiums in Enantioselective Synthesis 2003rd Table of contents:

• Chapter 1: The Design of Chiral Organolithium Reagents

  • (This chapter would likely discuss the fundamental principles and strategies for creating chiral organolithium species, focusing on how chirality is introduced and controlled.)

• Chapter 2: Enantioselective Additions of Organolithium Reagents to Carbonyl Compounds

  • (A key topic, covering the addition of organolithiums to aldehydes and ketones to form chiral alcohols, with an emphasis on asymmetric induction.)

• Chapter 3: Enantioselective Deprotonation and Lithium–Halogen Exchange Reactions

  • (Exploring the use of chiral lithium amide bases for enantioselective deprotonation, leading to chiral carbanions, and asymmetric lithium-halogen exchange.)

• Chapter 4: Organolithium Chemistry of Epoxides and Aziridines in Enantioselective Synthesis

  • (Focusing on the ring-opening reactions of strained cyclic ethers and amines with organolithiums, leading to enantiomerically enriched products.)

• Chapter 5: Asymmetric Synthesis with Chiral Organolithium Aggregates

  • (Discussing the role of aggregation in organolithium chemistry and how the structure of these aggregates influences stereoselectivity.)

• Chapter 6: Enantioselective Conjugate Addition Reactions of Organolithiums

  • (Reviewing 1,4-addition reactions of organolithiums to α,β-unsaturated carbonyl compounds and other Michael acceptors in an enantioselective manner.)

• Chapter 7: Chiral Ligands for Organolithium-Mediated Enantioselective Transformations

  • (A critical chapter focusing on the various types of chiral ligands used to control the stereochemistry of organolithium reactions, including diamines, amino ethers, and other chelating ligands.)

• Chapter 8: Tandem and Domino Reactions Involving Organolithiums in Enantioselective Synthesis

  • (Exploring multi-step sequences where organolithium reactions are integrated into more complex enantioselective synthetic strategies.)

• Chapter 9: Industrial Applications of Organolithiums in Asymmetric Synthesis

  • (Case studies and examples of how organolithium-mediated enantioselective reactions are used in the pharmaceutical or fine chemical industries.)

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Tags: David M Hodgson, Organolithiums, Enantioselective