Organometallic Compounds Of Lowcoordinate Si Ge Sn And Pb From Phantom Species To Stable Compounds Vladimir Ya Lee by Vladimir Ya. Lee, Akira Sekiguchi(auth.) 9780470669266, 9780470725436, 0470669268, 0470725435 instant download after payment.

Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species in organic chemistry. Topics covered include include the synthesis, structure, reactions and synthetic applications of :

• Si-, Ge-, Sn and Pb-centered cations, radicals and anions
• heavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes
• heavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes
• heavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers
• heteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes
• heavy analogues of alkenes of the type: >E14=E13-, >E14=E15-, >E14=E16 [where E13, E14, E15 and E16 are elements of the groups 13, 14, 15 and 16]
• cyclic compounds (three-, four-, five-, and six-membered rings)
• heavy analogues of 1,3-dienes, allenes and other cumulenes
• heavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity

Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistryContent:
Chapter 1 Heavy Analogs of Carbenium Ions: Si?, Ge?, Sn? and Pb?Centered Cations (pages 1–43):
Chapter 2 Heavy Analogs of Organic Free Radicals: Si?, Ge?, Sn? and Pb?Centered Radicals (pages 45–88):
Chapter 3 Heavy Analogs of Carbanions: Si?, Ge?, Sn? and Pb?Centered Anions (pages 89–138):
Chapter 4 Heavy Analogs of Carbenes: Silylenes, Germylenes, Stannylenes and Plumbylenes (pages 139–197):
Chapter 5 Heavy Analogs of Alkenes, 1,3?Dienes, Allenes and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb (pages 199–334):
Chapter 6 Heavy Analogs of Aromatic Compounds (pages 335–414):