Organozinc Derivatives And Transition Metal Catalysts Formation Of Cc Bonds By Crosscoupling Janine Cossy Editor by Janine Cossy (editor) 9783110728859, 3110728850 instant download after payment.

Organozinc reagents are less reactive than Grignard reagents but they　are much more chemoselective. Since the　Negishi cross-coupling reaction developed by Ei-ichi Negishi, who was awarded the Nobel Price in chemistry in 2010, a number of cross-coupling reactions involving organozinc derivatives and transition metal catalysts (Pd, Ni, Fe, Co, Cu, …) has been tuned up to form C-C bonds. This book on "Organozinc derivatives and transition metal catalysts" has been　written by experts in the field and is a complement to the book entitled "Grignard reagents and transition metal catalysts" (a De Gruyter book, edited by J. Cossy).

Grignard reagents or organozinc reagents, that is the question? From a given substrate, what is the best organometallic　reagent and the best transition metal to form a C-C bond by using a cross-coupling reaction? The solution might be found in these two books.

• Organozinc reagents are used in cross-coupling reactions and have better chemoselectivity and functional group tolerance than Grignard reagents.
• Catalysis of organozinc reagents using various metals for C-C bond formation is discussed.