Siliconmediated Transformations Of Functional Groups Prof Dr Helmut Vorbruggenauth by Prof. Dr. Helmut Vorbruggen(auth.) 9783527306688, 9783527603770, 3527306684, 3527603778 instant download after payment.

In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbrggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis.
Although every organic chemist may be familiar with different aspects of silylation for the protection of functional groups, this book covers the concept of protection while simultaneously silylating-activating various functional groups, such as amides and ureas. This novel methodology opens thus numerous synthetic pathways
while effecting the elimination of water in it volatile persilylated form under rather mild reaction conditions, which are often advantageous compared to conventional methods.
The compact form and clear structure of this monograph make this a long-awaited ready reference.
From the contents:
Introduction
* Techniques of Preparative Silylations-Desilylations
* Preparation and Properties of Siliconoxy-Leaving Groups
* Reactions of Free and Derivatized Carboxylic Acids and Carbon Dioxide
* Reactions of Aldehydes and Ketones
* Reactions of Alcohols, Ethers and Epoxides
* Reaction of N-O Systems
* Reactions of S-O and Se-O Systems
* Cyclizations and Ring Enlargements
* Base and Acid-Catalyzed as well as Thermal Eliminations of Trimethylsilanol. Peterson Reactions
* Formation of Carbon-Phosphorous Double- and Triple Bonds
* Reductions and Oxidations
* Dehydration-Activation as well as Silylation of Inorganic and Organic Salts and Metalorganic Compounds
* Formation of PolymersContent:
Chapter 1 Introduction (pages 1–5):
Chapter 2 Techniques for Preparative Silylations–Desilylations (pages 7–26):
Chapter 3 Preparation and Properties of Silyloxy Leaving Groups (pages 27–37):
Chapter 4 Reactions of Free and Derivatized Carboxylic Acids and Carbon Dioxide (pages 39–82):
Chapter 5 Reactions of Aldehydes and Ketones (pages 83–134):
Chapter 6 Reactions of Alcohols, Esters, Silyl Ethers, Epoxides, and Haloalkanes (pages 135–146):
Chapter 7 Reactions of N–O Systems (pages 147–188):
Chapter 8 Reactions of S–O and Se–O Systems (pages 189–215):
Chapter 9 Cyclizations and Ring Enlargements (pages 217–240):
Chapter 10 Base?Catalyzed, Acid?Catalyzed and Thermal Eliminations of Trimethylsilanol. Peterson Reactions (pages 241–252):
Chapter 11 Formation of Carbon–Phosphorus Double Bonds (pages 253–259):
Chapter 12 Reductions and Oxidations (pages 261–303):
Chapter 13 Dehydration – Halogenation – Activation and Silylation of Inorganic and Organic Salts and Metallorganic Compounds (pages 305–325):
Chapter 14 Formation of Organic and Inorganic Polymers (pages 327–333):